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Injection Molding Material Comparison — Property Table

Materials

Why material choice drives cost and performance

The resin you pick decides cycle time, tool wear, post-processing and end-use limits. Below is a working comparison of the plastics we mold most often for buyers weighing spec against budget — drawn from published material data and programs we have run.

The Snapshot

  • Service temperature spans the range: ABS ~80–100 °C to PEEK 250–260 °C, with PPS filling the 200–240 °C high-heat band.
  • Shrinkage drives DFM: amorphous resins (PC, PMMA, PS) shrink 0.2–0.7%; semi-crystalline (PP, PE, POM, PA) shrink 1.0–3.0% and need more draft.
  • Flame class varies by grade: enclosures near electronics often require UL94 V-0 (flame-out ≤10 s, no drips).
  • Real programs prove the table: a VR remote in PC+ABS held ±0.04 mm at 800K units/year; a PEEK-class MRI balun ran 15,000+ units/year in PEI.

Full property comparison table

Material Density (g/cm³) Service temp (°C) Tensile (MPa) Mold shrink (%) Melt temp (°C) Mold temp (°C) Typical use
ABS 1.05 80–100 40–50 0.4–0.7 200–260 40–80 Housings, brackets
PP (Polypropylene) 0.90 100–120 25–35 1.0–2.5 200–280 20–60 Hinges, living parts
PE (Polyethylene) 0.94 80–100 20–30 1.5–3.0 180–280 20–60 Containers, liners
PC (Polycarbonate) 1.20 115–130 60–70 0.5–0.7 280–320 80–120 Transparent, impact
POM (Acetal) 1.41 90–120 60–70 1.8–3.0 180–230 80–120 Gears, precision wear
PA (Nylon) 1.14 80–120 70–90 1.0–2.0 260–300 60–100 Bearings, structural
PEEK 1.32 250–260 90–100 1.1–1.4 350–400 160–200 Aerospace, medical
TPU 1.10–1.20 80–120 30–50 0.8–1.8 190–220 20–60 Soft-touch, gaskets
PMMA (Acrylic) 1.18 80–100 50–70 0.2–0.6 220–260 60–90 Optics, light pipes
PPS 1.35 200–240 70–90 0.2–0.6 300–340 120–160 Chemical, electrical
PVC 1.38 60–80 40–50 0.2–0.5 180–210 20–60 Profiles, enclosures
PS (Polystyrene) 1.05 70–90 40–55 0.4–0.7 200–260 20–60 Disposable, rigid

Shrinkage and resin class for DFM

Shrinkage above 2% (PP, PE, POM) demands more generous draft and tighter gate control. Amorphous resins (PC, PMMA, PS) hold tighter tolerances than semi-crystalline ones (PP, PE, POM). For humid environments, absorbent resins (PA, PBT) need drying before molding or you get splay.

A PA6-GF30 HV busbar program at 250,000+ units/year required pre-conditioning because moisture shifted dimensions by 0.2–0.5% — shrinkage and moisture are the two variables that break a tolerance if ignored.

Resin class summary:

  • Amorphous (PC, PMMA, PS, ABS): shrink 0.2–0.7%, dimensionally stable, lower warp, but lower chemical resistance and heat.
  • Semi-crystalline (PP, PE, POM, PA, PPS, PEEK): shrink 1.0–3.0% (except filled PPS/PEEK at 0.2–1.4%), higher chemical/heat resistance, more warp risk.

Glass-filled grades (PA66-GF30, PPS-GF40) shrink less (0.2–0.5%) but need weld-line and fiber-orientation control — the automotive connector in glass-filled PPS / PA66 held ±0.005 mm critical only with that control.

Heat, flame and moisture handling

Service temperature sets the floor; flame class sets the regulatory bar. UL94 classes in ascending severity: HB → V-2 → V-1 → V-0 → 5VA/5VB. V-0 means flame-out in ≤10 s with no burning drips — the common bar for enclosures near electronics.

  • ABS / PP / PC: often V-2 to V-0 by grade.
  • PPS / PEI / PEEK: inherently V-0 at 200–260 °C.
  • An NEV charging dust cover ran FR-TPU, UL94 V-0 at 500,000+ units/year.

Moisture handling by resin:

  • PA66: dry 80 °C, 4 h
  • PC: dry 120 °C, 4 h
  • POM: dry 80 °C, 2 h
  • PPS / PEEK: dry 150 °C, 3 h

Non-absorbent PP / PS / PE / LSR need little or no drying — a scheduling advantage for fast turnaround.

Decision shortcut by function

  • Need impact + transparency → PC (melt 280–320 °C)
  • Need living hinge → PP (melt 200–280 °C)
  • Need wear resistance + tight tolerance → POM or PEEK
  • Need soft-touch overmold → TPU / LSR
  • Need chemical/heat resistance → PPS or PEEK
  • Need lowest cost + light weight → PP (0.90 g/cm³)

Real programs behind the table

Program Material Tolerance Volume Lead time
Automotive connector Glass-filled PPS / PA66 ±0.005 mm 2M / yr 10 weeks
VR remote housing PC+ABS / TPE ±0.04 mm 800K / yr 9 weeks
Small button POM / ABS ±0.03 mm 5M / yr 12 weeks
Medical ECG button LSR (medical) ±0.03 mm 300K / yr 7 weeks
NEV dust cover FR-TPU (UL94 V-0) 500K / yr 6 weeks

Combining materials: overmolding and inserts

Many production parts are not one resin. Overmolding bonds a soft layer (TPE or LSR) onto a rigid substrate (ABS+PC, PA66), while insert molding casts plastic around a metal part (C11000 copper in the HV busbar, PA6-GF30 at 250,000+ units/year).

Design notes when combining:

  • Pick a TPE that bonds to your substrate (PC-ABS, PP) — mismatched chemistry delaminates.
  • Account for differential shrink (soft 0.8–1.8% vs rigid 0.4–0.7%) in the overmold gap.
  • Insert molding needs ±0.02 mm placement of the metal insert to avoid flash at PPS / PA66 gates.

Regulatory, sustainability and cost reading

Resin choice interacts with compliance:

  • RoHS / REACH: restrict heavy metals and SVHCs — relevant for ABS, PC, PPS imported to the EU.
  • UL94: flame class on the print for enclosures near electronics (V-0 = flame-out ≤10 s, no drips).
  • Recycled content: PP and ABS take post-consumer regrind at 10–30% with minor property loss; PEEK and PPS are rarely recycled in volume.
  • Medical / food: LSR and PEI are the biocompatible choices (the MRI balun ran PEI at 15,000+ units/year).

The property table is also a cost map. PP at $1–2.5/kg and 0.90 g/cm³ is the value floor; PEEK at $50–100/kg and 1.32 g/cm³ is the performance ceiling. Between them, ABS ($1.5–3/kg) and PA66 ($3–6/kg) cover most enclosures and structural parts.

When a quote looks expensive, check whether an engineering grade was specified where a commodity resin would do — moving PEEK to PPS can cut resin cost 5–10× while holding 200 °C+ service.

Talk to engineering before you finalize

Upload your 3D file and we return a material recommendation with DFM notes and the right flame class — not just a price. We match resin to load, temperature and budget, with lot-level material certification.

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